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posted by martyb on Friday April 28 2017, @04:27PM   Printer-friendly
from the now-that's-a-stretch dept.

Synthetic rubber and plastics - used for manufacturing tires, toys and myriad other products - are produced from butadiene, a molecule traditionally made from petroleum or natural gas. But those manmade materials could get a lot greener soon, thanks to the ingenuity of a team of scientists from three U.S. research universities.

The scientific team—from the University of Delaware, the University of Minnesota and the University of Massachusetts - has invented a process to make butadiene from renewable sources like trees, grasses and corn.

The findings, now online, will be published in the American Chemical Society's ACS Sustainable Chemistry and Engineering, a leading journal in green chemistry and engineering. The study's authors are all affiliated with the Catalysis Center for Energy Innovation (CCEI) based at the University of Delaware. CCEI is an Energy Frontier Research Center funded by the U.S. Department of Energy.

"Our team combined a catalyst we recently discovered with new and exciting chemistry to find the first high-yield, low-cost method of manufacturing butadiene," says CCEI Director Dionisios Vlachos, the Allan and Myra Ferguson Professor of Chemical and Biomolecular Engineering at UD and a co-author of the study. "This research could transform the multi-billion-dollar plastics and rubber industries."

Butadiene is the chief chemical component in a broad range of materials found throughout society. When this four-carbon molecule undergoes a chemical reaction to form long chains called polymers, styrene-butadiene rubber (SBR) is formed, which is used to make abrasive-resistant automobile tires. When blended to make nitrile butadiene rubber (NBR), it becomes the key component in hoses, seals and the rubber gloves ubiquitous to medical settings.

Abstract: Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran.

Not good news for Big Oil, which is already nervously eying electric vehicle advances.


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  • (Score: 2) by DannyB on Friday April 28 2017, @07:07PM

    by DannyB (5839) Subscriber Badge on Friday April 28 2017, @07:07PM (#501278) Journal

    Can they market that as Sustainable Global Warming? Maybe by executive order?

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