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MrPlow writes:

Submitted via IRC for Runaway1956

How seafood shells could help solve the plastic waste problem

Crustaceans' hardy shells contain chitin, a material that, along with its derivative chitosan, offers many of plastic's desirable properties and takes only weeks or months to biodegrade, rather than centuries.

The challenge is getting enough pure chitin and chitosan from the shells to make bio-based "plastic" in cost-effective ways. "There's no blueprint or operating manual for what we're doing," says John Keyes, CEO of Mari Signum, a start-up company based just outside of Richmond, Va., that is devising ways to make environmentally friendly chitin. But a flurry of advances in green chemistry is providing some guideposts.

[...] Entrepreneurs are trying to launch new chitin products. Cruz Foam, a company in Santa Cruz, Calif., set out to produce surfboards from chitin, though the company has since pivoted to focus on the much larger market of packaging foam. Polystyrene foam, a common component in both surfboards and food packaging, takes a minimum of 500 years to biodegrade. Company cofounder Marco Rolandi is convinced that his Cruz Foam will biodegrade readily, based on his at-home test. "I put Cruz Foam in my backyard compost and a month later there were worms growing on it," he says. Eco-friendly surfboards and wound dressings are valuable, but they are niche products — small potatoes that won't make a dent in the massive amounts of fossil fuel–based plastics. Scientists have proposed large-scale production of chitin or chitosan in the past. But the chemistry for isolating the materials from shell waste has some big drawbacks, so the work didn't get far.

[...] Approaches that reduce or eliminate corrosive reagents, recycle water and keep the polymers strong are in demand, says Pierre-Olivier Morisset of Merinov, a research center in Gaspé, Canada, that helps marine-product companies manage waste and commercialize innovations. "We're looking for technologies that can produce hundreds of kilograms" of chitin or chitosan with long polymer chains, Morisset says.

Advances in Functional Chitin Materials: A Review (DOI: 10.1021/acssuschemeng.8b06372) (DX)

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