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posted by martyb on Thursday June 25 2020, @05:59AM   Printer-friendly
from the heavy-metal dept.

An experiment suggested by a Ph.D. student may rewrite chemistry textbooks:

The project looked at a fundamental question: Which properties are inherent to a metal and which are incidental?

[...] The scientists cooled ammonia—normally a gas at room temperature—to minus 33 C to liquify it and then added, in separate experiments, the alkali metals lithium, sodium and potassium.

In these solutions, electrons from the alkali metal initially become trapped in the gaps between ammonia molecules. This creates what scientists call 'solvated electrons,' which are highly reactive but stabilized in the ammonia. These solutions have a characteristic blue color. But given enough solvated electrons, the whole liquid turns bronze and, in essence, becomes a metal while remaining liquid.

[...] The scientists next measured the amount of energy needed to bump the solvated electrons out of metallic ammonia using an extremely bright and focused X-ray beam based in Berlin.

In a first-ever experiment, they forced different concentrations of the metallic ammonia through a microjet, which created a stream about the width of a human hair that then passed through a hair-thin X-ray beam.

The results showed that, at low concentrations, solvated electrons were more easily dislodged from the solution by the interaction with the X-rays, giving a simple energy pattern. At higher concentrations, though, the energy pattern suddenly developed a sharp band edge, indicating the solution was behaving as a metal would.

Journal Reference:
Tillmann Buttersack, Philip E. Mason, Ryan S. McMullen, et al. Photoelectron spectra of alkali metal–ammonia microjets: From blue electrolyte to bronze metal [$], Science (DOI: 10.1126/science.aaz7607)


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  • (Score: 2) by driverless on Thursday June 25 2020, @12:34PM (1 child)

    by driverless (4770) on Thursday June 25 2020, @12:34PM (#1012367)

    If you expose certain materials to unrealistically exotic conditions then they behave in odd ways, which isn't really going to cause any chemistry books to be rewritten, in the same way that Newton's Laws aren't going to be erased by Einstein's later updates. Another example of this is that technically X-rays are a solid, although the conditions under which that occurs are also pretty exotic.

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  • (Score: 1, Funny) by Anonymous Coward on Thursday June 25 2020, @01:18PM

    by Anonymous Coward on Thursday June 25 2020, @01:18PM (#1012378)

    If you expose certain materials to unrealistically exotic conditions then they behave in odd ways

    That raysist.
    Freedom for all electrons!