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posted by cmn32480 on Thursday December 24 2015, @02:41AM   Printer-friendly
from the how-long-till-they-start-tracking-us-with-it dept.

Technology based on the use of high-performance lasers and sensors for the generation and detection of infrared light promises to be one of the key technologies of the 21st century. Realization of this goal will require the use of dyes that absorb light specifically in the near-infrared region of the spectrum, and such compounds are therefore of special interest to both researchers and commercial firms.

One class of chemicals that show great potential in this area are the so-called peri-arylenes which, thanks to their excellent stability properties, are already being used in a wide range of technical applications. A research team led by LMU [Loyola Marymount University] chemist Professor Heinz Langhals now reports the synthesis of the first peri-arylene consisting of six basic subunits, whose absorption spectrum is almost entirely confined to the near-infrared (NIR) region. In other words, the substance appears colorless to the human eye, and this makes it suitable for use as an inconspicuous labeling agent. The findings appear in the Journal of Organic Chemistry.

[...] The 6-member derivative absorbs essentially only in near-infrared region, which lies "below the red" and is therefore invisible to the human eye. "Fabrics dyed with the new compound appear colorless but the dyestuff can be detected with a suitable sensor," Langhals explains. One conceivable application for such a marker lies in the recycling of expensive textiles, since the compound would greatly simplify the sorting process. But in addition to the end-product of the synthesis, the shorter members of the series are also of considerable practical interest. This is because they exhibit intriguing light-induced responses, which may make them suitable for use in fluorescent solar collectors. "One other advantage of the new substances lies in their environmentally benign character: They consist entirely of organic materials that are biodegradable and fully combustible," Langhals adds.

Finally, a way for your mom to label your underwear without embarrassing you about it.

Sexterrylenetetracarboxylic Bisimides: NIR Dyes (DOI: 10.1021/acs.joc.5b02092)


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  • (Score: 3, Insightful) by frojack on Thursday December 24 2015, @03:15AM

    by frojack (1554) on Thursday December 24 2015, @03:15AM (#280492) Journal

    "Fabrics dyed with the new compound appear colorless but the dyestuff can be detected with a suitable sensor,"

    Other than the old saw about black and white not being colors, what exactly does "colorless fabric" look like?

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    • (Score: 0) by Anonymous Coward on Thursday December 24 2015, @05:22PM

      by Anonymous Coward on Thursday December 24 2015, @05:22PM (#280643)

      I think the point is that you could add this dye to a pattern with a thing saying 'this fabric is 90% cotton 10% poly' over and over across the entire fabric and it wouldn't make your pretty floral pattern look any different.

  • (Score: 3, Interesting) by linkdude64 on Thursday December 24 2015, @03:35AM

    by linkdude64 (5482) on Thursday December 24 2015, @03:35AM (#280497)

    Sounds like great tracking technology. Just like the secret dot patterns printed on your color laser printer: https://www.youtube.com/watch?v=sit6zUQKpJc [youtube.com]

  • (Score: 0) by Anonymous Coward on Thursday December 24 2015, @04:00AM

    by Anonymous Coward on Thursday December 24 2015, @04:00AM (#280507)

    ... using special goggles sold by Amazon and Google. Be the first on your block!

  • (Score: 2) by kurenai.tsubasa on Thursday December 24 2015, @04:08AM

    by kurenai.tsubasa (5227) on Thursday December 24 2015, @04:08AM (#280508) Journal

    I hope you all had a happy solstice! We continuing the celebration by watching all the science documentaries we couldn't watch on the 21st or 22nd! Merry Christmas, everyone, and a happy Gregorian new year!

  • (Score: 2) by Gravis on Thursday December 24 2015, @07:45AM

    by Gravis (4596) on Thursday December 24 2015, @07:45AM (#280552)

    i thought it would be interesting if some scientists incorporated NIR and UV elements into color advertisements so it would read something like, "if you can read this, call 1-800-XXX-XXXX to claim $10M reward" but only if you could see all five color ranges. it would be annoying to a small amount of tetrachromats to see partial messages but it would be a great way to actually find a true pentachromat.

    • (Score: 2) by hankwang on Thursday December 24 2015, @08:42AM

      by hankwang (100) on Thursday December 24 2015, @08:42AM (#280558) Homepage

      I doubt that there are any pentachromats that are sensitive to 945 nm (wavelength mentioned in the study). Molecules that can be excited at such long wavelengths (low photon energies) tend to be damaged by short (blue) wavelengths.

      A tetra/pentachromat will typically have extra receptor channels in the visible light range, causing them to perceive colors differently. But you can't print hidden messages for them. In daylight, a normal trichromat might not see the message, but under artificial light (line spectrum from a LED or HID lamp), the message would still show up.

      I think there are plenty of pentachromatic women. About 3% of males have a mutated red receptor (protanopia); 3% have a green mutation (deuteranopia), so about 0.1% have both. A female child of such a father will have five different color receptors. Unfortunately, the wiring to the brain will not use this information, just like it suppresses the information from rod (night vision) receptors in color perception.

      • (Score: 0) by Anonymous Coward on Thursday December 24 2015, @04:34PM

        by Anonymous Coward on Thursday December 24 2015, @04:34PM (#280615)

        HID lamps use black-body radiation (just at a higher color temperature)

        The real problem with GP's suggestion is that a large reward makes it practical to use specialized equipment to examine the poster. You would also have to control for the people at the print-shop knowing the message.

      • (Score: 2) by Gravis on Thursday December 24 2015, @06:19PM

        by Gravis (4596) on Thursday December 24 2015, @06:19PM (#280675)

        well i suppose they would be waiting a long time... until there actually is a proper pentachromat. ;)