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posted by Fnord666 on Tuesday September 26 2017, @07:49AM   Printer-friendly
from the unsinkable-beer-can dept.

http://aluminiuminsider.com/researchers-confirm-discovery-floating-aluminium/

Like most common metals, aluminium lacks natural buoyancy. However, with a little rearranging of the metal’s natural molecular structure, one can produce an ultra-light crystalline form of the metal that is actually less dense than water and, as a result, floats upon it.

Research conducted by Utah State University Department of Chemistry and Biochemistry professor Alexander Boldyrev and published in the latest issue of The Journal of Physical Chemistry C has yielded just such a crystalline form using computational modeling.

“My colleagues’ approach to this challenge was very innovative,” explained Boldyrev. “They started with a known crystal lattice, in this case, a diamond, and substituted every carbon atom with an aluminum tetrahedron.”

Boldyrev’s colleagues, namely Iliya Getmanskii, Vitaliy Koval, Rusian Minyaev, and Vladimir Minkin of Southern Federal University in Rostov-on Don, Russia, confirmed the structure which is metastable and has a density of 0.61 grams per cubic centimeter. By comparison, conventional aluminium possesses a density of 2.7 grams per cubic centimeter.


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  • (Score: -1, Offtopic) by Anonymous Coward on Tuesday September 26 2017, @08:06AM (1 child)

    by Anonymous Coward on Tuesday September 26 2017, @08:06AM (#572973)

    The only thing better than "Transparent Aluminium", with whales. But speaking of whales, has anyone seen the White Whale? You all know of the one of which I speak!

    "Queequeg," said I, "let's go; this fellow has broken loose from somewhere; he's talking about something and somebody we don't know."

    "Stop!" cried the stranger. "Ye said true- ye hav'n't seen Old Thunder yet, have ye?"

    "Who's Old Thunder?" said I, again riveted with the insane earnestness of his manner.

    "Captain Ahab."

    "What! the captain of our ship, the Pequod?"

    "Aye, among some of us old sailor chaps, he goes by that name. Ye hav'n't seen him yet, have ye?"

    "No, we hav'n't. He's sick they say, but is getting better, and will be all right again before long."

    "All right again before long!" laughed the stranger, with a solemnly derisive sort of laugh. "Look ye; when Captain Ahab is all right, then this left arm of mine will be all right; not before."

    "What do you know about him?"

    "What did they tell you about him? Say that!"

    "They didn't tell much of anything about him; only I've heard that he's a good whale-hunter, and a good captain to his crew."

    "That's true, that's true- yes, both true enough. But you must jump when he gives an order. Step and growl; growl and go- that's the word with Captain Ahab. But nothing about that thing that happened to him off Cape Horn, long ago, when he lay like dead for three days and nights; nothing about that deadly skrimmage with the Spaniard afore the altar in Santa?- heard nothing about that, eh? Nothing about the silver calabash he spat into? And nothing about his losing his leg last voyage, according to the prophecy. Didn't ye hear a word about them matters and something more, eh? No, I don't think ye did; how could ye? Who knows it? Not all Nantucket, I guess. But hows'ever, mayhap, ye've heard tell about the leg, and how he lost it; aye, ye have heard of that, I dare say. Oh, yes, that every one knows a'most- I mean they know he's only one leg; and that a parmacetti took the other off."

    "My friend," said I, "what all this gibberish of yours is about, I don't know, and I don't much care; for it seems to me that you must be a little damaged in the head. But if you are speaking of Captain Ahab, of that ship there, the Pequod, then let me tell you, that I know all about the loss of his leg."

    The Captain of the SoylentNews, avast there me maties, we know nothing about the loss of his leg!

    • (Score: 2) by FatPhil on Tuesday September 26 2017, @08:27AM

      by FatPhil (863) <{pc-soylent} {at} {asdf.fi}> on Tuesday September 26 2017, @08:27AM (#572981) Homepage
      Transparent aluminium was sooooo last season:
      https://phys.org/news/2017-07-russian-scientists-technology-production-transparent.html#nRlv
      (However, that wasn't the first transparent metal, that dates back to at least 2009: https://phys.org/news/2009-03-metal-transparent-high-pressure.html#nRlv )
      --
      Great minds discuss ideas; average minds discuss events; small minds discuss people; the smallest discuss themselves
  • (Score: 5, Informative) by c0lo on Tuesday September 26 2017, @08:08AM (19 children)

    by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @08:08AM (#572974) Journal

    To be accurate, TFT should read: "Scientists Compute Buoyant Aluminum".

    The abstract of TO(riginal)FA in the J. Phys. Chem. [acs.org] states:

    A new metastable ultra-light crystalline form of aluminum has been computationally designed using density functional calculations with imposing periodic boundary conditions...
    ...
    The new form of crystalline aluminum has extremely low density 0.61 g/cm3 and would float in water.

    No word of "have been realized/fabricated/brought into reality". It does NOT float on water, it would float on water.

    At such large spaces inside the lattice I imagine the crystal bond energy will make it reactive enough, because other lower energy states are stable (and this was computed as a metastable state)/
    As such, I expect that the material will never exist in the presence of oxygen - even when in the more dense crystalline form, aluminium forms an oxide layer over its surface. With increases spaces, I suspect oxygen will be able to penetrate deeper into the lattice and react, freeing an energy that will quickly "push down the energy well" the (supposed) material from its metastable state towards the more dense stable state.

    --
    https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
    • (Score: 3, Informative) by qzm on Tuesday September 26 2017, @08:28AM (1 child)

      by qzm (3260) on Tuesday September 26 2017, @08:28AM (#572982)

      That foamed Aluminium floats on water.
      As does Aluminium honeycomb.
      As of course does an Aluminium hull boat.

      Hell, we have inter-island barges with concrete hulls..

      And yes, I know thats not QUITE what they mean, but it goes point out how stupid the headline is.

      • (Score: 3, Funny) by FatPhil on Tuesday September 26 2017, @08:40AM

        by FatPhil (863) <{pc-soylent} {at} {asdf.fi}> on Tuesday September 26 2017, @08:40AM (#572987) Homepage
        But all that stuff sinks like a stone! A pumice stone, that is.
        --
        Great minds discuss ideas; average minds discuss events; small minds discuss people; the smallest discuss themselves
    • (Score: 2) by FatPhil on Tuesday September 26 2017, @08:37AM (16 children)

      by FatPhil (863) <{pc-soylent} {at} {asdf.fi}> on Tuesday September 26 2017, @08:37AM (#572985) Homepage
      Exactly the same thoughts went through my head - these are way bigger holes in the lattice than typical metallic aluminium. I also wonder whether, even if the oxide layer is non-porous, whether the oxygen bonds perturb the lattice structure, thereby weakening it, and perhaps even causing it to bloom how it does while being amalgamated (google mercury vs. aluminium, and waste some of your morning on what you find), and thus physically expose more surface area to more oxygen, with catastrophic consequences.

      Some lucky bastard is going to get the funding to play around with this and other experiments.
      --
      Great minds discuss ideas; average minds discuss events; small minds discuss people; the smallest discuss themselves
      • (Score: 2) by c0lo on Tuesday September 26 2017, @10:05AM (6 children)

        by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @10:05AM (#573011) Journal

        Some lucky bastard is going to get the funding to play around with this and other experiments.

        Which may not be that bad.
        After all, mass collapse from a metastable state is at the very base of lasers.
        E.g. I wonder what catalytic activity such a complex may show during the collapse.

        --
        https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
        • (Score: 2, Interesting) by khallow on Tuesday September 26 2017, @12:32PM (5 children)

          by khallow (3766) Subscriber Badge on Tuesday September 26 2017, @12:32PM (#573068) Journal

          E.g. I wonder what catalytic activity such a complex may show during the collapse.

          It's not a catalyst, if an irreversible process happens to it. Should be able to power certain kinds of reducing endothermic reactions. Might be reactive enough to strip the oxygen off of carbon dioxide though I imagine there are a bunch of reactive metals that have that property.

          • (Score: 2) by c0lo on Tuesday September 26 2017, @01:33PM (3 children)

            by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @01:33PM (#573090) Journal

            It's not a catalyst, if an irreversible process happens to it.

            Not a catalyst if it is consumed in the reaction.

            Otherwise, catalysts can become inactive [sciencedirect.com] over the reaction time and need to be reactivated

            While catalyst deactivation is inevitable for most processes, some of its immediate, drastic consequences may be avoided, postponed, or even reversed.

            In this case, the aluminium may not be consumed as a substance in the reaction, but may need to be reactivated by "blowing it up" again.

            --
            https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
            • (Score: 1) by khallow on Tuesday September 26 2017, @07:30PM (2 children)

              by khallow (3766) Subscriber Badge on Tuesday September 26 2017, @07:30PM (#573424) Journal

              Otherwise, catalysts can become inactive [sciencedirect.com] over the reaction time and need to be reactivated

              The reactivation is the reversal of the process. And it is usually something simple like heating, washing, or mechanically shaking the catalyst.

              In this case, the aluminium may not be consumed as a substance in the reaction, but may need to be reactivated by "blowing it up" again.

              "Blowing it up" isn't going to be a simple process and may involve as much energy as a normal chemical reaction.

              • (Score: 2) by c0lo on Tuesday September 26 2017, @09:58PM (1 child)

                by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @09:58PM (#573533) Journal

                "Blowing it up" isn't going to be a simple process and may involve as much energy as a normal chemical reaction.

                Which may worth doing if the reaction is entirely exotic - i.e. does not happen except in the presence of blown up aluminium.

                --
                https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
                • (Score: 1) by khallow on Tuesday September 26 2017, @11:16PM

                  by khallow (3766) Subscriber Badge on Tuesday September 26 2017, @11:16PM (#573557) Journal
                  That still doesn't make it a catalyst.
          • (Score: 0) by Anonymous Coward on Tuesday September 26 2017, @09:20PM

            by Anonymous Coward on Tuesday September 26 2017, @09:20PM (#573516)

            Magnesium will burn in a carbon dioxide atmosphere.

      • (Score: 4, Insightful) by MostCynical on Tuesday September 26 2017, @10:07AM (7 children)

        by MostCynical (2589) on Tuesday September 26 2017, @10:07AM (#573012) Journal

        "Blew up small containment vessel and laboratory.
        Conclusion: need more funding for larger laboratory and containment vessel."

        --
        "I guess once you start doubting, there's no end to it." -Batou, Ghost in the Shell: Stand Alone Complex
        • (Score: 2) by c0lo on Tuesday September 26 2017, @10:17AM (6 children)

          by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @10:17AM (#573017) Journal

          And it will happen if it shows potential for military applications.

          --
          https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
          • (Score: 2) by MostCynical on Tuesday September 26 2017, @10:36AM (5 children)

            by MostCynical (2589) on Tuesday September 26 2017, @10:36AM (#573025) Journal

            All new, non-recyclable coke cans! Get em before they're too hot to handle!

            For the military, I can see it all depending on how controlled the (inevitable) state change will e this stuff could make a great alternative to compression ignition for bullets. - no hammer needed just something to penetrate the protective layer.

            Does anyone know if "meta" in metastable really just means "theoretically"?

            --
            "I guess once you start doubting, there's no end to it." -Batou, Ghost in the Shell: Stand Alone Complex
            • (Score: 2) by FatPhil on Tuesday September 26 2017, @11:05AM (4 children)

              by FatPhil (863) <{pc-soylent} {at} {asdf.fi}> on Tuesday September 26 2017, @11:05AM (#573032) Homepage
              "Metastable" is basically "stable as long as you don't trigger it". Supercooled liquids can be happy to remain liquid a long way below freezing point, but smack them or introduce crystalisation sites, and they'll quite happily leave that state en masse. Super-saturated solutions too. And lasers (collapse from the excited state being the laser pulse). And feminists.
              --
              Great minds discuss ideas; average minds discuss events; small minds discuss people; the smallest discuss themselves
              • (Score: 2, Touché) by c0lo on Tuesday September 26 2017, @11:40AM (3 children)

                by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @11:40AM (#573043) Journal

                And feminists.

                I'm yet to see a metastable feminist.
                Maybe I need to see one during her deepest slumber, while heavily sedated.

                --
                https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
                • (Score: 1, Touché) by Anonymous Coward on Tuesday September 26 2017, @03:56PM

                  by Anonymous Coward on Tuesday September 26 2017, @03:56PM (#573203)

                  It's a very transient state. Just after the finish of a rant, there is a very brief pause before the intake of breath that powers the next rant.

                • (Score: 2) by MostCynical on Wednesday September 27 2017, @01:55AM (1 child)

                  by MostCynical (2589) on Wednesday September 27 2017, @01:55AM (#573612) Journal

                  Hold on - which one of you is sedated?

                  --
                  "I guess once you start doubting, there's no end to it." -Batou, Ghost in the Shell: Stand Alone Complex
                  • (Score: 2) by c0lo on Wednesday September 27 2017, @03:34AM

                    by c0lo (156) Subscriber Badge on Wednesday September 27 2017, @03:34AM (#573650) Journal

                    Interesting perspective.

                    --
                    https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
      • (Score: 2) by VLM on Tuesday September 26 2017, @11:52AM

        by VLM (445) on Tuesday September 26 2017, @11:52AM (#573047)

        I wonder if the hole size is big enough to make an interesting filter.

        I wonder if a surface like that would have exciting catalytic properties.

  • (Score: 0, Funny) by Anonymous Coward on Tuesday September 26 2017, @10:14AM

    by Anonymous Coward on Tuesday September 26 2017, @10:14AM (#573016)

    This is obviously fake Russian propaganda meant to interfere in the US's democratic metallurgy process, and Julian Assange is clearly working behind the scenes on behalf of the FSB and GRU.

    I demand congressional hearings into this outrageous foreign corruption of our free smelting system by attempting to influence American molecules in the way they crystallize. Has Jared Kushner ever been in Rostov? Does Donald Trump use aluminum in his airplanes?

    How can we allow sinister Russian agents like biochemistry professor Alexander Boldyrev to taint our precious bodily metals?

    /parody

  • (Score: 1, Interesting) by Anonymous Coward on Tuesday September 26 2017, @10:52AM (4 children)

    by Anonymous Coward on Tuesday September 26 2017, @10:52AM (#573029)

    More space between metal atoms in crystal lattice means more hydrogen can be absorbed.
    Hopefully it won't make it even more explosive if exposed to oxygen ...

    Hmm, what happens if D-soaked light aluminum suddenly collapses?

    Will we have nuclear fusion?

    If yes, will we have deep sub-critical nuclear munition?

    If yes, how brave a grunt has to be to carry around a weapon with a full magazine of rounds which each can go off "just because I'm metastable"?

    OK, my thoughts are starting to disperse now. Someone please jump in and continue.

    • (Score: 4, Informative) by c0lo on Tuesday September 26 2017, @12:23PM (3 children)

      by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @12:23PM (#573060) Journal

      More space between metal atoms in crystal lattice means more hydrogen can be absorbed.

      If you don't find a way to keep it there, I reckon all that space is useless.

      Hmm, what happens if D-soaked light aluminum suddenly collapses? Will we have nuclear fusion?

      I really doubt it - after all, we are dealing with energy barriers (for fusion) at the order 10 keV.
      Now, suppose that a cubic cage of 8 Al atoms would collapse with such a force to cause two D to fuse - which means 500keV stored by 8 atoms
      27g of Al is a mole - Avogadro's number says 6.023e23 atoms.
      Which mean 7.25e22 individual cages of 8 atoms, with no corners/sides shared between them
      If each cage can perform a work of 10keV and 1keV is 1.6e-16, the entire energy in those 7.25e22 cages will be 120.46MJ. That's the equivalent of 28kg of TNT in 27g of metastable floating aluminium.

      Without a weird screening effect on the coulomb field of the trapped hydrogen (and lowering the coulomb barrier 100-1000 times less), fusion's not gonna happen.

      If yes, how brave a grunt has to be to carry around a weapon with a full magazine of rounds which each can go off "just because I'm metastable"?

      Feeling of guts: about 200g-300g of pure-ethanol-induced bravery for an 85kg grunt body? I don;t know, perhaps eth-fueled can step in with his expertise.
      Or perhaps 3 to 5 worth of American-football concussions?

       

      --
      https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
      • (Score: 2) by c0lo on Tuesday September 26 2017, @12:25PM

        by c0lo (156) Subscriber Badge on Tuesday September 26 2017, @12:25PM (#573061) Journal

        Correction "which means 500keV 10keV stored by 8 atoms".
        The following computations uses the 10keV value though.

        --
        https://www.youtube.com/watch?v=aoFiw2jMy-0 https://soylentnews.org/~MichaelDavidCrawford
      • (Score: 2) by deimtee on Tuesday September 26 2017, @04:02PM

        by deimtee (3272) on Tuesday September 26 2017, @04:02PM (#573210) Journal

        28kg vs 27 g is a factor of about a thousand. Given that TNT is actually pretty shitty energy storage, that's a lot closer to being possible than I would have guessed.

        --
        If you cough while drinking cheap red wine it really cleans out your sinuses.
      • (Score: 3, Funny) by bob_super on Tuesday September 26 2017, @07:21PM

        by bob_super (1357) on Tuesday September 26 2017, @07:21PM (#573411)

        > 3 to 5 worth of American-football concussions

        New unit for behavior : My congressman is running at about 76 AFC.

  • (Score: 0) by Anonymous Coward on Tuesday September 26 2017, @02:21PM (1 child)

    by Anonymous Coward on Tuesday September 26 2017, @02:21PM (#573117)

    Boldyrev’s colleagues, namely Iliya Getmanskii, Vitaliy Koval, Rusian Minyaev, and Vladimir Minkin of Southern Federal University in Rostov-on Don, Russia, confirmed the structure which is metastable and has a density of 0.61 grams per cubic centimeter.

    So basically, this is russion research for which the US professor is taking credit?

    • (Score: 2) by Spamalope on Tuesday September 26 2017, @03:26PM

      by Spamalope (5233) on Tuesday September 26 2017, @03:26PM (#573172) Homepage

      It's a funding ruse. The Russians will get this material first if you don't fund my lab!

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