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Diamond Nanowires Assemble Themselves

Accepted submission by takyon at 2016-12-27 02:57:36
Science

Scientists have created diamond nanowires [stanford.edu] that could be used for electronics and other applications:

Scientists at Stanford University and the Department of Energy's SLAC National Accelerator Laboratory have discovered a way to use diamondoids – the smallest possible bits of diamond – to assemble atoms into the thinnest possible electrical wires, just three atoms wide.

[...] "What we have shown here is that we can make tiny, conductive wires of the smallest possible size that essentially assemble themselves," said Hao Yan, a Stanford postdoctoral researcher and lead author of the paper. "The process is a simple, one-pot synthesis. You dump the ingredients together and you can get results in half an hour. It's almost as if the diamondoids know where they want to go."

[...] They started with the smallest possible diamondoids – single cages that contain just 10 carbon atoms – and attached a sulfur atom to each. Floating in a solution, each sulfur atom bonded with a single copper ion. This created the basic nanowire building block. The building blocks then drifted toward each other, drawn by the van der Waals attraction between the diamondoids, and attached to the growing tip of the nanowire.

"Much like LEGO blocks, they only fit together in certain ways that are determined by their size and shape," said Stanford graduate student Fei Hua Li, who played a critical role in synthesizing the tiny wires and figuring out how they grew. "The copper and sulfur atoms of each building block wound up in the middle, forming the conductive core of the wire, and the bulkier diamondoids wound up on the outside, forming the insulating shell."

The article includes a GIF animation of the structure.

Hybrid metal–organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly [nature.com] (DOI: 10.1038/nmat4823) (DX [doi.org])


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